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It would be a private adoption, and yes, she can sign them over. You'd be required to notify the agency because they need to know your capacity and also about who is in your house.
If this looks like a serious option, I'd ask to be put on hold. At least until you meet the mom and see if you are an option. The last thing that those poor kids will need is dealing with a foster sibling.
Cannot imagine the pain that woman is going through.